Alloying Mechanisms for Epitaxial Nanocrystals

Alloying mechanisms for epitaxial nanocrystals.

The different mechanisms involved in the alloying of epitaxial nanocrystals are reported in this Letter. Intermixing during growth, surface diffusion, and intraisland diffusion were investigated by varying the growth conditions and annealing environments during chemical vapor deposition. The relative importance of each mechanism was evaluated in determining a particular composition profile for ...

Rapid and High-Efficiency Laser-Alloying Formation of ZnMgO Nanocrystals

Applications of ZnMgO nanocrystals (NCs), especially in photoelectric detectors, have significant limitations because of the unresolved phase separation in the synthesis process. Here, we propose a rapid and highly efficient ZnMgO NC alloying method based on pulsed laser ablation in liquid. The limit value of homogeneous magnesium (Mg) is pushed from 37% to 62%, and the optical band gap is incr...

Shaping binary metal nanocrystals through epitaxial seeded growth.

Morphological control of nanocrystals has become increasingly important, as many of their physical and chemical properties are highly shape dependent. Nanocrystal shape control for both single- and multiple-material systems, however, remains empirical and challenging. New methods need to be explored for the rational synthetic design of heterostructures with controlled morphology. Overgrowth of ...

Tailoring the Morphology and the Optical Properties of Semiconductor Nanocrystals by Alloying

Epitaxial II-VI tripod nanocrystals: a generalization of van der Waals epitaxy for nonplanar polytypic nanoarchitectures.

We report for the first time the synthesis of nonplanar epitaxial tripod nanocrystals of II-VI compounds (ZnO, ZnS, ZnSe, ZnTe, CdS, CdSe, and CdTe) on muscovite mica substrate. With CdS as a case study, we conclude via Raman spectroscopy and electron microscopy studies that the tripods, which are found to be polytypic, followed a seeded growth mechanism. The epitaxy, manifested by the in-plane...